Abstract
EQUILIBRIUM AND STABILITY ANALYSIS OF METAL CHELATES OF ND AND PR METALS WITH P CHLOROBENZALDEHYDETHIOSEMICARBAZONE SYSTEM
Dr. Gopal Chhetri*
ABSTRACT
Co-ordination compounds now days deserving attention due to their wide use in bio-chemisty.analytical chemistry and in agriculture industries(8), co-ordination compounds of thiosemicarbazone (ligand) with Nd, Pr, Gd, Eu etc shows their use as an anticancer properties(1-3) so it required more attention . In order to understand nature of bonding between metals and the ligand in solution and to determine the stability in solution study is essential and important .in present study varies parameters which are useful are calculated by using change in pH of ligand and its metal complex at 28oC and 38oC ,Formation constants, free energy change, entropy change and heat of reactions also calculate to determine the feasibility of complex formation.
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