Abstract
STABILITY CONSTANTS OF MIXED LIGAND COMPLEXES OF TRANSITION METAL (II) IONS WITH 4-BROMO-2-{(E)-[(2-METHYL-5-NITROPHENYL) IMINO]METHYL}PHENOL AND 1-{(E)-[(4-METHOXY-2-METHYLPHENYL) IMINO]METHYL}NAPHTHALEN-2-OL.
Atmaram K. Mapari*
ABSTRACT
Binary and ternary complexes of the type M-Y and M-X-Y [M = Co(II), Ni(II), Cu(II) and Zn(II); X = 4-bromo-2-{(E)-[(2-methyl-5-nitrophenyl)imino]methyl}phenol and Y = 1-{(E)-[(4-methoxy-2-methylphenyl)imino]methyl}naphthalen-2-ol] have been examined pH-metrically at27 ± 0.5oC and at constant ionic strength, ? = 0.1 M (KCl) in 75 : 25 (v/v) 1,4-dioxne-water medium. The stability constants for Binary (M-Y) and ternary (M-X-Y) systems were calculated.
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